Triethylamine-promoted elimination from (R,R)-PhCHORCHClCO2Me (R = MeCO, PhCO, 4-MeC6H4, 4-MeOC6H4, MeSO2 and 4-MeC6H4SO2) in various solvents

Authors
Montani, RS Gil, E Cabaleiro, MC
Citation
Rs. Montani et al., Triethylamine-promoted elimination from (R,R)-PhCHORCHClCO2Me (R = MeCO, PhCO, 4-MeC6H4, 4-MeOC6H4, MeSO2 and 4-MeC6H4SO2) in various solvents, J CHEM R-S, (2), 1999, pp. 138-139
Citations number
13
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
2
Year of publication
1999
Pages
138 - 139
Database
ISI
SICI code
0308-2342(199902):2<138:TEF((=>2.0.ZU;2-M
Abstract
The rates and stereochemistry of elimination from a number of (R,R)-PhCHORC HClCO2Me (R = MeCO, PhCO, 4-MeC6H4, 4-MeOC6H4, MeSO2 and 4-MeC6H4SO2) with triethylamine in tetrahydrofuran, acetone, methanol, dimethylformamide and acetonitrile as solvents led to the conclusion that the elimination process occurs through an (E1cB)(I) mechanism.