Configurational properties of cyclonona-1,2,4,5,7,8-hexaene and cyclododeca-1,2,5,6,9,10-hexaene

Authors
Yavari, I Norouzi-Arasi, H Nori-Shargh, D Fallah-Bagher-Shaidaei, H
Citation
I. Yavari et al., Configurational properties of cyclonona-1,2,4,5,7,8-hexaene and cyclododeca-1,2,5,6,9,10-hexaene, J CHEM R-S, (2), 1999, pp. 154-155
Citations number
15
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
2
Year of publication
1999
Pages
154 - 155
Database
ISI
SICI code
0308-2342(199902):2<154:CPOCAC>2.0.ZU;2-K
Abstract
AM1 semi-empirical SCF MO calculations for the structure optimization and c onfigurational properties of cyclonona-1,2,4,5,7,8-hexaene 3, its hexamethy l derivative 4 and cyclododeca-1,2,5,6,9,10-hexaene 5 show that the combina tion of three allenic units of the same chirality yields an enantiomeric pa ir which is the most stable configuration of 3, 4 and 5.