Sodium periodate epoxidation of alkenes catalysed by manganese porphyrins

Authors
Mohajer, D Tayebee, R Goudarziafshar, H
Citation
D. Mohajer et al., Sodium periodate epoxidation of alkenes catalysed by manganese porphyrins, J CHEM R-S, (2), 1999, pp. 168-169
Citations number
25
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
2
Year of publication
1999
Pages
168 - 169
Database
ISI
SICI code
0308-2342(199902):2<168:SPEOAC>2.0.ZU;2-8
Abstract
Epoxidation of alkenes with different electronic and steric properties has been performed with high selectivity by sodium periodate in the presence of acetatotetraarylporphinatomanganese(III) complexes containing electron rel easing or withdrawing groups at the ortho positions of the aryl rings, in a two-phase (CH2Cl2-H2O) medium at 24 +/- 2 degrees C.