Cp. Liu et al., Quantitative analysis of ultrathin doping layers in semiconductors using high-angle annular dark field images, J MICROSC O, 194, 1999, pp. 171-182
It is well known that the high-angle annular darli field (HAADF technique i
n scanning transmission electron microscopy is an incoherent imaging proces
s in the lateral try) plane. However, as a consequence of the existence of
partial coherence in the z direction, accurate quantitative interpretation
of image intensity is difficult. The effects of coherence in the z directio
n can be reduced by increasing the inner collector angle of the annular det
ector so that the scattering from atoms in the z direction is essentially i
ncoherent, We thus show that it is feasible to quantify the total As concen
tration of ultrathin InAsxP1-x layers in InP in a simple but accurate way u
sing a thickness integrated Bloch wave calculation including phonon scatter
ing with a large inner collector angle of the annular detector of around 15
0 mrad. We compare the As composition derived from this approach with that
from the Fresnel method and high resolution imaging, We also show that the
non-linear variation of the HAADF intensity with thickness is consistent wi
th our simpler simulations for such conditions. Therefore, this approach en
ables us easily and quickly to quantify compositions using HAADF images. Th
e tetragonal distortion due to lattice mismatch is also shown to influence
the contrast and has been included in the calculations.