Erbium-doped LiNbO3 plates were produced by the ion exchange process; Compo
sitional in-depth analysis of the species involved in the process, performe
d by secondary ion mass spectrometry, showed that the multivalent Er3+-3Li(
+) ion exchange occurs. Moreover, active properties of Er3+ ions in LiNbO3
were evidenced by photoluminescence spectroscopy. A systematic study on the
role of ion exchange parameters was performed showing that erbium incorpor
ation took place under different regimes. The method was demonstrated to be
suitable for Er-doping of LiNbO3 crystals, with the possibility of control
ling the optical performances of the material through the preparation param
eters. (C) 1999 Elsevier Science B.V. All rights reserved.