Separation of uranium and thorium using tris(2-ethylhexyl) phosphate as extractant

Citation
Pn. Pathak et al., Separation of uranium and thorium using tris(2-ethylhexyl) phosphate as extractant, J RAD NUCL, 240(1), 1999, pp. 15-18
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
240
Issue
1
Year of publication
1999
Pages
15 - 18
Database
ISI
SICI code
0236-5731(199904)240:1<15:SOUATU>2.0.ZU;2-X
Abstract
The distribution behavior of uranium and thorium has been investigated in a biphasic system of different aqueous nitric acid concentrations and a solu tion of tris(2-ethylhexyl) phosphate (TEHP) in n-dodecane at 25 degrees C. The effect of different uranium and thorium concentrations in the aqueous p hase on the extraction of these metal ions is evaluated. These results indi cate that TEHP is a better choice than tri-n-butyl phosphate (TBP) for the separation of U-233 from the irradiated thorium matrix.