The effect of diluents on the extraction of uranium(VI) with petroleum sulf
oxides (PSO) was studied. The decreasing order of extraction ability of PSO
is as follows: benzene, toluene, cyclohexane, heptane, kerosene, carbon te
trachloride and chloroform. The effect of temperature on the extraction equ
ilibrium was also investigated and enthalpy of the extraction was obtained.
The relationship between the extraction equilibrium constants K-ex and the
physical parameters of diluents can be derived.