INTRINSIC RESONANCE REPRESENTATION OF QUANTUM-MECHANICS

Citation
M. Carioli et al., INTRINSIC RESONANCE REPRESENTATION OF QUANTUM-MECHANICS, The Journal of chemical physics, 106(20), 1997, pp. 8564-8571
Citations number
35
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
106
Issue
20
Year of publication
1997
Pages
8564 - 8571
Database
ISI
SICI code
0021-9606(1997)106:20<8564:IRROQ>2.0.ZU;2-Y
Abstract
The choice of basis states in quantum calculations can be influenced b y several requirements, and sometimes a very natural basis suggests it self. However often one retreats to a ''merely complete'' basis, whose coefficients in the eigenstates carry Little physical insight. We sug gest here an optimal representation, based purely on classical mechani cs. ''Hidden'' constants of the motion and good actions already known to the classical mechanics are thus incorporated into the basis, leavi ng the quantum effects to be isolated and included by small matrix dia gonalizations. This simplifies the hierarchical structure of couplings between ''zero-order'' states. We present a (non-perturbative) method to obtain such a basis-state as solutions to a certain resonant Hamil ton-Jacobi equation. (C) 1997 American Institute of Physics.