When a 1-mol%-Fe2O3-added 0.67BaTiO(3)-0.33SrTiO(3) (mole ratio) powder com
pact was sintered at 1380 degrees C, a core-shell structure was developed.
The core phase formed via solid-state interdiffusion of barium and strontiu
m ions between BaTiO3 and SrTiO3 particles. In contrast, the shell phase fo
rmed via a solution-precipitation process in the presence of an Fe2O3-conta
ining liquid phase. Energy-dispersive X-ray analysis showed that the core w
as a strontium-rich paraelectric phase and the shell was a barium-rich ferr
oelectric phase at room temperature. The core-shell structure developed in
the BaTiO3-SrTiO3 system suggests the possibility of obtaining a variety of
phase distributions with different Curie temperatures.