The PTCR effect was investigated in the ferroelectric BaNb2O6 phase doped w
ith TiO2. Composite ceramics formed after sintering in a reducing atmospher
e and subsequent reoxidation show the PTCR effect at around 70 and 300 degr
ees C, respectively. Both PTCR anomalies are associated with the formation
of high resistivity grain boundaries after controlled oxidation of reduced
constituent phases. (C) 1999 Elsevier Science Limited. All rights reserved.