Jf. Roeder et al., Ferroelectric strontium bismuth tantalate thin films deposited by metalorganic chemical vapour deposition (MOCVD), J EUR CERAM, 19(6-7), 1999, pp. 1463-1466
Thin films of Sr1-xBi2+xTa2O9 (SBT) have been deposited by metalorganic che
mical vapor deposition (MOCVD) on 150 mm Si wafers with Pt/Ti electrodes. T
he choice of Bi precursor significantly affects the process; film homogenei
ty is significantly improved when using a beta-diketonate Bi precursor in c
ombination with compatible Sr and Ta precursors. A highly repeatable proces
s has been developed, with good run-to-run composition and thickness contro
l. Effects of Bi volatility have been investigated in annealing experiments
that show the onset of Bi loss at similar to 570 degrees C at reduced pres
sure (1-10 Torr). Film properties relevant to integrated ferroelectric rand
om access (Fe RAMS) memories have also been characterized. Remenant polariz
ations (2P(r)) up to 24 mu C cm(-2) have been obtained at 5 V, with 90% sat
uration of 2P(r) at 1.5 V and a coercive voltage of 0.52 V for a 140 mn fil
m. Electrical leakage current density values were <2x10(-8) A cm(-2) at 1.5
V. Fatigue endurance has been measured to 10(11) cycles with < 10% degrada
tion in switched charge. (C) 1999 Elsevier Science Limited. All rights rese
rved.