Reactions of organogermylenes generated by photolysis of 7-germanorbornadienes and cyclohexagermanes with organic halides and trimethyltin chloride

Authors
Adachi, M Mochida, K Wakasa, M Hayashi, H
Citation
M. Adachi et al., Reactions of organogermylenes generated by photolysis of 7-germanorbornadienes and cyclohexagermanes with organic halides and trimethyltin chloride, MAIN GR MET, 22(4), 1999, pp. 227-230
Citations number
23
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
22
Issue
4
Year of publication
1999
Pages
227 - 230
Database
ISI
SICI code
0792-1241(199904)22:4<227:ROOGBP>2.0.ZU;2-#
Abstract
Reactions of organogermylenes, R2Ge: (R=Me and Pr-1), generated by photolys is of 7-germanorbornadienes and cyclohexagermanes with organic halides (R'X ) were examined by chemical trapping experiments and CIDNP measurements. Th e organogermylenes reacted quantitatively with polyhalomethanes (XCCl3, X=C l, Br) and benzyl bromide to give the corresponding abstraction products to gether with polyhaloethanes and bibenzyl, respectively. With trimethyltin c hloride the organogermylenes afforded effectively the insertion products.