Evidence of very strong [2x nu(NO)] overtones when adsorbing NO in Cu-I,Cu-II-exchanged Y zeolites

Authors
Palomino, GT Bordiga, S Zecchina, A
Citation
Gt. Palomino et al., Evidence of very strong [2x nu(NO)] overtones when adsorbing NO in Cu-I,Cu-II-exchanged Y zeolites, PCCP PHYS C, 1(8), 1999, pp. 2033-2035
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PCCP PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
1
Issue
8
Year of publication
1999
Pages
2033 - 2035
Database
ISI
SICI code
1463-9076(19990415)1:8<2033:EOVS[N>2.0.ZU;2-G
Abstract
In this communication the first vibrational results obtained in "transmissi on" mode, concerning NO/Cu-Y systems, containing Cu-I and Cu-II ions, are p resented. The IR spectra of these systems are characterized by strong and w ell defined IR peaks, both in the v(NO) and 2 x v(NO) stretching regions. P lausible physical reasons justifying the unusual and astonishing high inten sity of the peaks in the 2 x v(NO) overtone region are discussed.