We have investigated the behavior of the 2p3s3p, 2p3p3p, and 2p3s3s Auger l
ines of NiO, a model compound in the class of strongly correlated 3d system
s, while varying the photon energy across the Ni L-3 and L-2 absorption edg
es. The experimental data are discussed in comparison with a theoretical mo
del based on a charge-transfer multiplet approach. When the excitation ener
gy is below the L-3 resonance, we observe the 2p3p3p and 2p3s3p peaks at a
constant binding energy. This behavior is typical of nonradiative resonant
Raman scattering. If the photon energy is increased further, the 2p3p3p and
2p3s3p lines rapidly transform into constant kinetic energy features, show
ing a normal Auger behavior. The transition from Raman- to Auger-like behav
ior takes place for photon energies lower than the ones corresponding to ex
citations of the photoelectron into ligand-hole states. This might indicate
the participation of inelastic processes in the recombination of the core
hole involving energies much smaller than the NiO gap, or the possible pres
ence of nonlocal effects. On the high photon energy side of the L-3 edge, t
he constant kinetic energy of the 2p3p3p and 2p3s3p peaks is systematically
larger than the one observed for an excitation well above the L-2,L-3 edge
s. We attribute this behavior to the intervention of an intermediate state
of 2p(5)3d(10) character, which has very little weight but is strongly enha
nced at resonance. [S0163-1829(99)06215-3].