STM and LEED observations of the surface structure of TiO2(110) following crystallographic shear plane formation

Extended vacuum annealing of rutile TiO2(110) produces macroscopic and nano scopic changes in the surface morphology. These result from the ordering of oxygen vacancies/Tin+ interstitials in bulk TiO2 into crystallographic she ar (CS) planes. We have employed low-energy electron diffraction (LEED) and scanning tunnelling microscopy (STM) to identify the surface termination o f CS planes produced in the bulk. The directions of the planar defects alon g the surface indicate the {132} series of shear planes dominate the STM im ages, which is also supported by the LEED results. The spacing between plan es gradually varies across the surface suggesting that a series of Magneli phases are formed. LEED patterns confirm the coexistence of both relatively large areas of a single phase and a continuum of separations between plane s. Formation of CS planes also leads to extensive facetting of the crystal, which is visible to the naked eye as a rippled surface finish. Some Ca seg regation is observed during CS plane formation; however, when removed the C S planes remain, indicating they are not significantly stabilized by the Ca . [S0163-1829(99)02215-8].