Non-equilibrium carrier dynamics in silicon quantum wires is theoretically
investigated taking into account the existence of two coupled subsystems: f
ree carriers and excitons. The filling of space among the wires by dielectr
ic medium results in the decrease in binding energy of excitons and thus th
eir concentration and at the same time in the increase in free carrier conc
entration. Modification of the relation between the exciton concentration a
nd free carrier density changes the relaxation time of nonequilibrium carri
ers. The model is experimentally proved using the time-resolved methods of
photoluminescence and IR free carrier absorption in porous silicon.