Ma. Ruggiero et Jw. Rutter, ORIGIN OF MICROSTRUCTURE IN THE 332 K EUTECTIC OF THE BI-IN-SN SYSTEM, Materials science and technology, 13(1), 1997, pp. 5-11
Specimens of the 332 K eutectic of the Bi-In-Sn system were solidified
unidirectionally at low speeds and quenched to form a representative
solid/liquid interface for subsequent study. The solid/liquid interfac
es of all three solidifying phases, BiIn2, gamma-Sn and beta-In, were
found to be of the non-faceted type and the resulting eutectic interfa
ce was flat and isothermal. At all growth rates used, an intimate mixt
ure of the three phases was formed. At low growth rates, the microstru
cture was found to approximate a three phase fibrous structure, while
at higher growth rates it tended to be lamellar, with lamellae alterna
ting in the sequence -gamma Sn-BiIn2-beta-In-BiIn2-gamma-Sn-BiIn2-beta
-In-. The phase spacing was found to follow the usual law: lambda(2)R
= constant, where lambda is the phase spacing, and R is the growth rat
e. The microstructure formed is compared with that of ternary eutectic
s that contain faceting phases, studied earlier.