A. Scacco et al., Thermally activated processes in the relaxed excited states of aggregate color centers in KF : Na, RADIAT EFF, 146(1-4), 1998, pp. 323-329
Optical absorption and photoluminescence spectra of KF crystals, doped with
small concentrations of Na impurities and additively colored, are measured
in order to determine thermally activated processes between different exci
ted states of the F-A centers. The mechanism of transformation of F-A cente
rs from type I (at low temperature) to type II (al higher temperatures) is
fully confirmed by the anticorrelated temperature dependences of the intens
ities of the two F-A(Na) luminescences peaking at 900 and 2150 nm.