Synthesis and characterisation of mixed N-(salicylidene)-(o)under-bar-mercaptoaniline alkyldithiocarbonate derivatives of antimony(III)

Authors
Singh, MS Rao, KP
Citation
Ms. Singh et Kp. Rao, Synthesis and characterisation of mixed N-(salicylidene)-(o)under-bar-mercaptoaniline alkyldithiocarbonate derivatives of antimony(III), SYN REAC IN, 29(4), 1999, pp. 541-551
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
4
Year of publication
1999
Pages
541 - 551
Database
ISI
SICI code
0094-5714(199904)29:4<541:SACOMN>2.0.ZU;2-2
Abstract
Mixed N-(salicylidene)-(o)under-bar-mercaptoaniline alkyldithiocarbonate de rivatives of antimony(III) have been synthesized by substitution reactions of chlorobis[N-(salicylidene)-(o)-under-bar-mercaptoaniline]antimony(III), Sb[SC6H4N=C(H)C6H4OH](2)Cl. dichloro[N-(salicylidene)-(o)under-bar-mercapto aniline]antimony(III), Sb[SC6H4N=C(H)C6H4O]Cl-2 and monochloro[N-(salicylid ene)-(o)under-bar-mercaptoaniline]antimony(III), Sb[SC6H4N=C(H)C6H4O]Cl wit h potassium alkyl xanthates in benzene/carbon disulfide in 1:1, 1:2 and 1:1 molar ratios, respectively. The yellow or orange crystalline complexes hav e been characterized by elemental analyses, melting points, molecular weigh t determinations as well as IR and NMR (H-1 and C-13) spectroscopy.