Reaction of (mu(3)-Se)RuCo2(CO)(9): Synthesis and crystal structure of thechiral skeleton clusters (mu(3)-Se)RuCoM(CO)(8)[C5H3(CH3)(COCH3)] (M = Mo,W)

Authors
Ding, ER Wu, SL Li, QS Yin, YQ Sun, J
Citation
Er. Ding et al., Reaction of (mu(3)-Se)RuCo2(CO)(9): Synthesis and crystal structure of thechiral skeleton clusters (mu(3)-Se)RuCoM(CO)(8)[C5H3(CH3)(COCH3)] (M = Mo,W), SYN REAC IN, 29(4), 1999, pp. 565-575
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
4
Year of publication
1999
Pages
565 - 575
Database
ISI
SICI code
0094-5714(199904)29:4<565:RO(SAC>2.0.ZU;2-Y
Abstract
The reaction of (mu 3-Se)RuCo2(CO)(9) (1) with the functionally substituted cyclopentadienyl tricarbonyl metal anions M-(CO)(3)C5H3[(CH3)(COCH3)] (M = Mo, W) in reluxing THF gave new chiral skeleton clusters (mu(3)-Se)RuCoM(C O)(8)[C5H3(CH3)(COCH3)] [M = Mo (4), W (5)]. X-ray data for (4) show that i t is orthorhombic, space group Pbca, a = 13.712(7) Angstrom, b = 16.451(8) Angstrom, c = 18.44(1) Angstrom, V = 4158(6) Angstrom(3), Z = 8, Dc = 2.172 g/cm(3), R = 0.073 and Rw = 0.087.