Synthesis of cyclitols via ring-closing metathesis

Citation
A. Kornienko et M. D'Alarcao, Synthesis of cyclitols via ring-closing metathesis, TETRAHEDR-A, 10(5), 1999, pp. 827-829
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
5
Year of publication
1999
Pages
827 - 829
Database
ISI
SICI code
0957-4166(19990312)10:5<827:SOCVRM>2.0.ZU;2-C
Abstract
A convenient synthesis of enantiomerically pure and differentially protecte d L-chiro- and myo-inositols as well as conduritols B and F from 2,3,4-tri- O-benzyl-D-xylopyranose via ring-closing metathesis is reported. The facile synthesis of conduritol B constitutes a short formal synthesis of (-)-cycl ophellitol. (C) 1999 Elsevier Science Ltd. All rights reserved.