The influence of thermal annealing on the surface and interface roughness o
f epitaxial Ag/Pd superlattices has been quantitatively characterized by hi
gh-angle X-ray diffraction and atomic force microscopy. Although Ag and Pd
form a continuous series of solid solutions, it is shown that thermal annea
ling of the layered structure does not lead to complete interdiffusion, but
rather to a clustering of the individual components. The bulk phase diagra
m of materials is clearly not the only factor determining the structural pr
operties of thin layers in superlattices. (C) 1999 Elsevier Science S.A. Al
l rights reserved.