The proton drip line defines one of the fundamental limits to nuclear stabi
lity. Nuclei lying beyond this line are energetically unbound to the emissi
on of a constituent proton from their ground states. This phenomenon is kno
wn as proton radioactivity. For near-spherical nuclei in the region of the
drip line between Z = 69 (Tm) and Z = 81 (Tl), proton decay transition rate
s have been shown to be well reproduced by WKB calculations using spectrosc
opic factors derived from a low-seniority shell model calculation. Another
approach using spectroscopic factors obtained from the independent quasipar
ticle approximation has also proved successful in this region. These interp
retations have allowed the extraction of nuclear structure information from
nuclei well beyond the proton drip line. The race-earth proton emitters Ho
-141 and Eu-131 have recently been observed, and their decay rates can only
be explained by assuming large deformation for these nuclei. In addition t
o providing information on the wavefunctions and deformations of these nucl
ei, these results offer the opportunity to study the phenomenon of quantum
mechanical tunneling through a deformed potential barrier.