Fe/Al multilayers are prepared by crossed-beam pulsed laser deposition and
investigated by Rutherford backscattering, conversion electron Mossbauer sp
ectroscopy, and transmission electron microscopy, The results are compared
to purely ballistic simulations of the deposition process using the TRIDYN4
.0 code. It is found that the intermixing of adjacent layers must be descri
bed in terms of ballistic mixing followed by chemical mixing. The phase for
mation in the transition layer between adjacent layers follows the nonequil
ibrium behavior of Fe/Al in analogy to investigations on mechanically alloy
ed and ion-beam-mixed Fe/Al, In Fe-rich areas a bcc solid solution is forme
d. In Al-rich environment an amorphous phase is observed.