Interfacial reactions of Gd on both (111) and (001)Si have been investigate
d. An amorphous interlayer (a-interlayer) is formed at the initial stage of
reactions of RE metal thin films on Si systems. The growth of amorphous ph
ase was followed by the nucleation of the crystalline silicide at the a-int
erlayer/Si interface. Both hexagonal GdSi2-x (h-GdSi2-x) and orthorhombic G
dSi2 (o-GdSi2) were observed to form in (001) and (111) samples. Crystallin
e defects such as vacancy ordering and stacking faults were observed and an
alyzed. (C) 1999 Published by Elsevier Science B.V. All rights reserved.