Novel extended linear structure of decavanadate anions linked by bis(4-pyridinium) disulfide (H(2)dpds), {(H(2)dpds)(2)[V10O26(OH)(2)]center dot 10H(2)O}(n)

Authors
Kondo, M Fujimoto, K Okubo, T Asami, A Noro, S Kitagawa, S Ishii, T Matsuzaka, H
Citation
M. Kondo et al., Novel extended linear structure of decavanadate anions linked by bis(4-pyridinium) disulfide (H(2)dpds), {(H(2)dpds)(2)[V10O26(OH)(2)]center dot 10H(2)O}(n), CHEM LETT, (4), 1999, pp. 291-292
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
4
Year of publication
1999
Pages
291 - 292
Database
ISI
SICI code
0366-7022(199904):4<291:NELSOD>2.0.ZU;2-U
Abstract
New porous coordination polymer, {(H(2)dpds)(2)[V10O26(OH)(2)] . 10H(2)O}(n ) (H(2)dpds = bis(4-pyridinium) disulfide), was synthesized and structurall y characterized. X-ray analysis demonstrates that the decavanadate anions a re doubly bridged by H(2)dpds ligands to provide a one-dimensional structur e. This network affords channeling cavities with dimension of about 2 x 4 A ngstrom along the c-axis.