Hydrothermal synthesis of Fe-montmorillonite in Si-Fe-Mg system

Authors
Nagase, T Iwasaki, T Ebina, T Hayashi, H Onodera, Y Dutta, NC
Citation
T. Nagase et al., Hydrothermal synthesis of Fe-montmorillonite in Si-Fe-Mg system, CHEM LETT, (4), 1999, pp. 303-304
Citations number
9
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
4
Year of publication
1999
Pages
303 - 304
Database
ISI
SICI code
0366-7022(199904):4<303:HSOFIS>2.0.ZU;2-F
Abstract
Fe-montmorillonite (Na0.3Fe1.73+Mg0.3Si4O10(OH)(2) . H2O) was synthesized h ydrothermally for 24 hours at 100 and 200 degrees C. XRD analysis showed th e synthesized material to be crystalline Fe-montmorillonite without impurit ies, with d(001) = 11-14.3 Angstrom and d(06) = 1.52-1.53 Angstrom, respect ively. The particle size of the material was found to be > 500 Angstrom by TEM. The X-ray photoelectron binding energy of Fe indicated that iron is pr esent in smectite as Fe3+.