Mechanism of lithium insertion in carbons pyrolyzed at low temperature

Citation
Hq. Xiang et al., Mechanism of lithium insertion in carbons pyrolyzed at low temperature, CHIN SCI B, 44(5), 1999, pp. 385-390
Citations number
34
Categorie Soggetti
Multidisciplinary
Journal title
CHINESE SCIENCE BULLETIN
ISSN journal
10016538 → ACNP
Volume
44
Issue
5
Year of publication
1999
Pages
385 - 390
Database
ISI
SICI code
1001-6538(199903)44:5<385:MOLIIC>2.0.ZU;2-5
Abstract
Carbons pyrolyzed at temperature ranging from 500 degrees C to 1 000 degree s C are promising materials for high-energy density lithium batteries. Thes e carbons not only possess a capacity higher than the theoretical value of graphite, but also display a different electrochemical behavior from that o f graphite. Mechanisms now available for this phenomenon are reviewed after the presentation of mechanism of lithium intercalation in graphite. Based on the recent research, a new model for lithium insertion in carbons pyroly zed at low temperature and some ideas for further study are proposed.