The electropolymerization of different azines from aqueous solutions was in
vestigated. The structure of monomers was systematically varied changing bo
th the nature of the second heteroatom and the substituents in the aromatic
rings. Considering the electropolymerization process and the properties of
the resulting polymers one can denote polyazines as a new group of electro
active polymers. The electrochemical and spectroelectrochemical investigati
on of polyazines was done. A hypothesis on azine polymer structure is prese
nted.