Preparation and structural investigations of (dippNSiMe(3)Si)(2)(Cp*Ti)(2)(NH)(6) (dipp = 2,6-iPr(2)C(6)H(3)), [dippNSiMe(3)Si(NH2)NH](3) and [dippNSiMe(3)Ge(NH2)NH](3)

Authors
Wraage, K Schmidt, HG Noltemeyer, M Roesky, HW
Citation
K. Wraage et al., Preparation and structural investigations of (dippNSiMe(3)Si)(2)(Cp*Ti)(2)(NH)(6) (dipp = 2,6-iPr(2)C(6)H(3)), [dippNSiMe(3)Si(NH2)NH](3) and [dippNSiMe(3)Ge(NH2)NH](3), EUR J INORG, (5), 1999, pp. 863-867
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
5
Year of publication
1999
Pages
863 - 867
Database
ISI
SICI code
1434-1948(199905):5<863:PASIO(>2.0.ZU;2-U
Abstract
The reaction of dippNSiMe(3)Si(NH2)(3) (1) (dipp = 2,6-iPr(2)C(6)H(3)) with Cp*TiMe3 (Cp* = C5Me5) and Me3SnCl yields the new heterocyclic adamantane (dippNSiMe(3)Si)(2)(Cp* Ti)(2)(NH)(6) (2) containing the Si2Ti2(NH)(6) core and the silicon-nitrogen six-membered ring compound [dippNSiMe(3)Si-(NH2)N H](3) (4). [dippNSiMe(3)Ge(NH2)(2)](2)NH (5) reacts with AlMe3 to give the germanium-nitrogen six-membered ring compound [dippNSiMe(3)Ge(NH2)NH](3) (6 ). The compounds 2, 4 and 6 have been structurally characterized by single- crystal X-ray structural analysis.