Feldspar metasomatism along a Proterozoic rift-basin margin - "Smoke" around a base-metal "fire" (HYC deposit, Australia) or a product of background diagenesis?
Gj. Davidson, Feldspar metasomatism along a Proterozoic rift-basin margin - "Smoke" around a base-metal "fire" (HYC deposit, Australia) or a product of background diagenesis?, GEOL S AM B, 111(5), 1999, pp. 663-673
The relationship between regional alkali-feldspar metasomatism and the alte
ration around large, sediment-hosted, stratiform Zn-Pb deposits is not well
understood. At the Proterozoic HYC deposit in the Northern Territory, Aust
ralia, feldspar alteration of volcaniclastic beds (similar to 85 thin beds
within a 700-m-thick section) forms a wedge (in plan view >2 km wide) that
is zoned westward from microcline to albite away from the Emu fault zone, w
hich forms the half-graben margin. In cross section, the base-metals deposi
t occurs near the bottom of the feldspar-altered wedge and has a similar,wi
dth, However, similar feldspar alteration occurs at several more poorly exp
osed points regionally along the Emu fault; base-metal sulfides are absent
at these sites, Whole rock and delta(18)O(whole rock) geochemistry indicate
that, the feldspar forming fluid was cool (32 +/- 27 degrees C) and had a
delta(18)O composition that is most consistent with a meteoric origin (-12
parts per thousand +/- 6 parts per thousand). A fluid with these characteri
stics is not considered suitable for base-metal transport; in addition, tex
tural evidence indicates that the main feldspar alteration of the volcanicl
astic beds predated the base-metal mineralization in most examples, To acco
unt for the activity of two fluids leading to the low-temperature feldspar
alteration and the spatially coincident high-temperature base-metal deposit
ion, I propose that meteoric ground water from the adjacent horst was focus
ed into the shale-filled basin by a long-lived, shallow, saline fluid flow
This fluid preferentially reacted with vitroclastic rocks in the upper diag
enetic zone. The extent of the feldspar and microquartz alteration was prop
ortional to the head generated by transpression along the Emu fault zone (i
.e., the basin margin). Salts were leached from a carbonate-evaporite seque
nce within the fault zone without substantially altering the delta(18)O com
position of the fluid, The westward zonation from microcline to albite was
achieved by K-feldspar deposition during brink migration, which isothermall
y increased the Na/K ratio in the fluid until albite was stabilized, Base-m
etal deposition occurred separately by the episodic fault release of high-t
emperature, deep-basin brines, producing disseminated Mn-Fe carbonate, adul
aria, pyrite, and base-metal sulfides in some volcaniclastic beds, The hydr
ogeochemical model may be generally applicable to provinces in which synsed
imentary faults juxtaposed arid subaerial regions against volcaniclastic-be
aring marine basins, inducing basinward saline fluid flow.