Structural and spectroscopic characterisation of the mixed valence platinum complex PtdabI(3) (dab = o-diaminobenzene)

Authors
Danzeisen, OF Goanta, M Rotter, HW Thiele, G
Citation
Of. Danzeisen et al., Structural and spectroscopic characterisation of the mixed valence platinum complex PtdabI(3) (dab = o-diaminobenzene), INORG CHIM, 287(2), 1999, pp. 218-222
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
287
Issue
2
Year of publication
1999
Pages
218 - 222
Database
ISI
SICI code
0020-1693(19990430)287:2<218:SASCOT>2.0.ZU;2-F
Abstract
The new mixed valence platinum complex PtdabI(3) (dab = o-diaminobenzene) ( 1) has been prepared and characterised. The crystal structure consists of s eparate units of planar Pt(II)dabI(2) and octahedral Pt(IV)dabI(4) molecule s. The latter are arranged in linear chains with rather short intermolecula r I ... I-contacts (3.478 Angstrom) which are responsible for charge transf er interactions. In the resonance Raman spectrum strong intensity enhanceme nts and extended overtone progressions of the symmetric I-Pt-I stretching m ode have been observed. (C) 1999 Elsevier Science S.A. All rights reserved.