Synthesis, characterization and X-ray structural determination of the nine-coordinate tris-aqua tetra-oxamato neodymium(III) complex [Nd(Hoxm)(3)(H(2)oxm) center dot 2.5H(2)O](n)

Authors
Veltsistas, PG Papadimitriou, CD Slawin, AMZ Woollins, JD
Citation
Pg. Veltsistas et al., Synthesis, characterization and X-ray structural determination of the nine-coordinate tris-aqua tetra-oxamato neodymium(III) complex [Nd(Hoxm)(3)(H(2)oxm) center dot 2.5H(2)O](n), J CHEM R-S, (3), 1999, pp. 222-223
Citations number
17
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
3
Year of publication
1999
Pages
222 - 223
Database
ISI
SICI code
0308-2342(199903):3<222:SCAXSD>2.0.ZU;2-G
Abstract
The reaction of Nd-III with oxamic acid yields [Nd(Hoxm)(3)(H(2)oxm). 2.5H( 2)O](n) 1 (H(2)oxm = oxamic acid) which contains nine-coordinate Nd centres linked into chains via four-coordinate Hoxm(-) ligands; the chains are con nected via an array of H-bonds.