Synthesis, characterization and X-ray structural determination of the nine-coordinate tris-aqua tetra-oxamato neodymium(III) complex [Nd(Hoxm)(3)(H(2)oxm) center dot 2.5H(2)O](n)
Pg. Veltsistas et al., Synthesis, characterization and X-ray structural determination of the nine-coordinate tris-aqua tetra-oxamato neodymium(III) complex [Nd(Hoxm)(3)(H(2)oxm) center dot 2.5H(2)O](n), J CHEM R-S, (3), 1999, pp. 222-223
The reaction of Nd-III with oxamic acid yields [Nd(Hoxm)(3)(H(2)oxm). 2.5H(
2)O](n) 1 (H(2)oxm = oxamic acid) which contains nine-coordinate Nd centres
linked into chains via four-coordinate Hoxm(-) ligands; the chains are con
nected via an array of H-bonds.