The standard molar enthalpies of formation of 5,10,15,20-tetraphenylporphine and 5,10,15,20-tetrakis(4-methoxyphenyl)porphine by oxygen bomb combustion calorimetry
R. Patino et al., The standard molar enthalpies of formation of 5,10,15,20-tetraphenylporphine and 5,10,15,20-tetrakis(4-methoxyphenyl)porphine by oxygen bomb combustion calorimetry, J CHEM THER, 31(5), 1999, pp. 627-634
The standard massic energies of combustion Delta(u)u(0) at T = 298.15 K wer
e determined from combustion calorimetry experiments for solid 5,10,15,20-t
etraphenylporphine (TPP, Chemical Abstracts registry number 917-23-7) and 5
,10,15,20-tetrakis (4-methoxyphenyl) porphine (TMPP, Chemical Abstracts reg
istry number 221 12-7 8-3), leading to the following results:
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where Delta(c)U(m)(0), Delta(c)H(m)(0), and Delta(f)H(m)(0) denote the stan
dard molar energy of combustion, standard molar enthalpy of combustion, and
standard molar enthalpy of formation, respectively. The values of the deri
ved standard molar enthalpies of formation differ significantly from the on
ly known literature results, especially for TMPP. It is concluded that the
final results are strongly dependent on the purity of the samples. (C) 1999
Academic Press.