VOQ(2)OH or [VOQ(2)-O-VOQ(2)] (Q=8-hydroxyquinolinate)? A classic monomer dimer dilemma revisited

Authors
Parajon-Costa, BS Gonzalez-Baro, AC Baran, EJ
Citation
Bs. Parajon-costa et al., VOQ(2)OH or [VOQ(2)-O-VOQ(2)] (Q=8-hydroxyquinolinate)? A classic monomer dimer dilemma revisited, J COORD CH, 47(3), 1999, pp. 417-424
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
47
Issue
3
Year of publication
1999
Pages
417 - 424
Database
ISI
SICI code
0095-8972(1999)47:3<417:VO[(AC>2.0.ZU;2-Z
Abstract
The electrochemical behavior of VOQ(2)OH or [VOQ(2)-O-VOQ(2)] (Q = 8-hydrox yquinolinate anion) has been investigated by cyclic voltammetry in acetonit rile solutions. Although both species exist simultaneously at every conditi on analyzed, they can be clearly differentiated by this method. The effect of trace amounts of water on the electrochemical behavior is also discussed .