Synthesis and properties of addition compounds between triphenylphosphine-oxide(TPPO) and lanthanide trifluoromethanesulfonates

Authors
Alencar, FL Zinner, LB Zinner, K Matos, JEX
Citation
Fl. Alencar et al., Synthesis and properties of addition compounds between triphenylphosphine-oxide(TPPO) and lanthanide trifluoromethanesulfonates, J COORD CH, 46(4), 1999, pp. 471-478
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
00958972 → ACNP
Volume
46
Issue
4
Year of publication
1999
Pages
471 - 478
Database
ISI
SICI code
0095-8972(1999)46:4<471:SAPOAC>2.0.ZU;2-5
Abstract
Additon compounds between triphenylphosphine-oxide and trifluoromethanesulf onates are synthesized and characterized by microanalyses, electrolytic con ductance, vibrational (infrared) spectra, absorption spectra in the visible region and thermogravimetric procedures. The results are in agreement with the formulas La(CF3SO3)(3).3TPPO . 4H(2)O and Ln(CF3SO3)(3).4TPPO. The lig ands (TPPO) coordinate through the phosphoryl oxygen. Complex interactions with solvents of different donating capacities are also found. Thermogravim etric studies result in lanthanide trifluoride products.