Structural characterization of components of a mixture-characterization ofa facile oxidation product of cryptolepinone in situ

Citation
Ce. Hadden et al., Structural characterization of components of a mixture-characterization ofa facile oxidation product of cryptolepinone in situ, J HETERO CH, 36(2), 1999, pp. 525-531
Citations number
14
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF HETEROCYCLIC CHEMISTRY
ISSN journal
0022152X → ACNP
Volume
36
Issue
2
Year of publication
1999
Pages
525 - 531
Database
ISI
SICI code
0022-152X(199903/04)36:2<525:SCOCOA>2.0.ZU;2-2
Abstract
The nmr analysis of a mixture of cryptolepinone and it's 5(N)-oxide in a 1. 5:1 ratio is discussed. The differentiation of the resonances of the two si milar compounds, and elucidation of the unknown 5(N)-oxide relied primarily on IDR-GHSQC-TOCSY data in conjunction with ROESY, GHSQC, and GHMBC experi ments.