Citation
Hw. Lam et al., Structure and total synthesis of benzylthiocrellidone, a novel dimedone-based vinyl sulfide from the sponge Crella spinulata, J CHEM S P1, (8), 1999, pp. 847-848
Citations number
8
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
0300922X
→ ACNP
Issue
8
Year of publication
1999
Pages
847 - 848
Database
ISI
SICI code
0300-922X(19990421):8<847:SATSOB>2.0.ZU;2-E
Abstract
A concise synthesis of the yellow pigment benzylthiocrellidone 1, based on
a Michael addition-elimination of dimedone 2 to the ketone thioacetal 7 der
ived from dimedone, benzyl bromide ana carbon disulfide, is described. The
synthetic pigment had an X-ray crystal structure identical to that measured
for the natural product.