This paper reports an extended experimental investigation, using the b
eam-foil technique, of the intensity ratio of the fine-structure compo
nents in the 3s(2)3p P-2(1/2, 3/2) 3s3p(2) S-2(1/2) and P-2(1/2) reson
ance transitions along the A1I isoelectronic sequence. These intensity
ratios are strongly influenced by cancellation/enhancement effects ar
ising from spin-orbit induced level mixings, and are thus sensitive pr
obes of the detailed atomic structure. New data are given for Si II, P
III, S IV, K VII, Sc IX, Fe XIV and Ni XVI. Together with previous ex
perimental results this comprehensive isoelectronic study reveals sign
ificant and systematic deviations from theoretical predictions.