Satellites of multiple ionization in auger K-spectra of neon-like molecules

Auger K-spectra of all neon-like molecules (HF, H2O, NH3, and CH4 are calcu lated with satellites of multiple ionization taken into account. In the cal culation of probabilities of Auger transitions,electron density of ligands, multiplet splitting, and interaction of configurations of final states are taken into account simultaneously. Theoretical integral intensities of sha ke-off and shake-up satellites "with observer" in Auger K-spectra of neon-l ike molecules are 18.2-20.5% of the total intensity of the Auger spectrum. The inclusion of satellites of multiple ionization makes it possible to int erpret certain features of molecular Auger spectra.