1,2-dimetalated benzene derivatives (1,2-C6H4MCH3)(n) of group 13 (M = Al,Ga, In)

Authors
Dam, MA Nijbacker, T de Kanter, FJJ Akkerman, OS Bickelhaupt, F Spek, AL
Citation
Ma. Dam et al., 1,2-dimetalated benzene derivatives (1,2-C6H4MCH3)(n) of group 13 (M = Al,Ga, In), ORGANOMETAL, 18(9), 1999, pp. 1706-1709
Citations number
43
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
9
Year of publication
1999
Pages
1706 - 1709
Database
ISI
SICI code
0276-7333(19990426)18:9<1706:1BD(OG>2.0.ZU;2-H
Abstract
Reaction of (o-phenylene)magnesium (1) with CH3MCl2 (2; M = Al, Ga, In) gav e access to the corresponding methyl(o-phenylene)metal compounds 3 ((1,2-C6 H4MCH3)(n)). These novel 1,2-dimetalated benzene derivatives of group 13 we re characterized by their spectral data and, in the case of 3b (M = Ga, n = 2), by a single-crystal X-ray structure determination.