Synthesis and characterization of ruthenium-osmium complexes containing mu-bisalkenyl, mu-alkenylvinylidene, and mu-alkenylcarbene bridge ligands

Authors
Buil, ML Esteruelas, MA
Citation
Ml. Buil et Ma. Esteruelas, Synthesis and characterization of ruthenium-osmium complexes containing mu-bisalkenyl, mu-alkenylvinylidene, and mu-alkenylcarbene bridge ligands, ORGANOMETAL, 18(9), 1999, pp. 1798-1800
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
9
Year of publication
1999
Pages
1798 - 1800
Database
ISI
SICI code
0276-7333(19990426)18:9<1798:SACORC>2.0.ZU;2-A
Abstract
The metaloalkyne complex Ru{(E)-CH=CH-(CH2)(4)-C equivalent to CH}Cl(CO)((P Pr3)-Pr-i)(2) reacts with OsHCl(CO)-((PPr3)-Pr-i)(2) to give the heterodinu clear-mu-bisalkenyl derivative ((PPr3)-Pr-i)(2)(CO)ClRu{(E)-CH=CH-(CH2)(4)- CH=CH-(E)}OsCl(CO)((PPr3)-Pr-i)(2) via the hydrido-vinylidene intermediate ((PPr3)-Pr-i)(2)(CO)ClRu{(E)-CH=CH-(CH2)(4)- CH=C}-OsHCl(CO)((PPr3)-Pr-i)(2 ). The reaction of the heterodinuclear-mu-bisalkenyl complex with HCl selec tively affords ((PPr3)-Pr-i)(2)(CO) ClRu{(E)-CH=CH-(CH2)(5)-CH}OsCl2(CO)-(( PPr3)-Pr-i)(2).