HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2' 6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE)/

Authors
CHOTALIA R CONSTABLE EC HANNON MJ TOCHER DA
Citation
R. Chotalia et al., HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2' 6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE)/, Journal of the Chemical Society. Dalton transactions, (22), 1995, pp. 3571-3580
Citations number
84
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
22
Year of publication
1995
Pages
3571 - 3580
Database
ISI
SICI code
0300-9246(1995):22<3571:HL-SAT>2.0.ZU;2-L
Abstract
A series of complexes containing hypodentate didentate 2,2':6',2 ''-te trpyridine (terpy) ligands of general formula [Ru(L-N,N')(2)(terpy-N,N ')](2+) [L = 2,2'-bipyridine (bipy) or 1,10-phenanthroline] have been prepared. The complexes [Ru(bipy-N,N')(2)(terpy-N,N')][PF6](2) and [Ru (bipy-N,N')(2)(bterpy-N,N')][PF6](2) (bterpy = 6-bromo-2,2':6'2 ''-ter pyridine) have been structurally characterised and shown to contain th e didentate terpy ligand in the solid state.