Synthesis, molecular structure and radical scavenging effect of octanuclear thiolate zinc complex [NMe4](2)[(c-mu(4)-S)(mu-SCH2Ph)(12)S4Zn8]

Authors
Guo, SL Ding, E Chen, H Yin, YQ Li, XJ
Citation
Sl. Guo et al., Synthesis, molecular structure and radical scavenging effect of octanuclear thiolate zinc complex [NMe4](2)[(c-mu(4)-S)(mu-SCH2Ph)(12)S4Zn8], POLYHEDRON, 18(5), 1999, pp. 735-740
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
18
Issue
5
Year of publication
1999
Pages
735 - 740
Database
ISI
SICI code
0277-5387(1999)18:5<735:SMSARS>2.0.ZU;2-P
Abstract
The new cage-like octanuclear thiolate complex [NMe4](2)[(c-mu(4)-S)(mu-SCH 2Ph)(12)S4Zn8] has been prepared and characterized by X-ray crystal structu re analysis. All eight Zn atoms and a mu(4)-S constitute a tetracapped tetr ahedron, in which mu(4)-S is at the center of cage. The suppression abiliti es of the complex for the hydroxyl and TEMP radicals were determined by EPR and GC, and the results showed that the complex possess more effective sup pression abilities than natural MT. (C) 1999 Elsevier Science Ltd. All righ ts reserved.