A novel photoinduced electron transfer reaction of N-alkylphenothiazines in carbon tetrachloride
Citation
X. Guo et al., A novel photoinduced electron transfer reaction of N-alkylphenothiazines in carbon tetrachloride, SCI CHINA B, 42(2), 1999, pp. 170-177
Categorie Soggetti
Chemistry
Journal title
SCIENCE IN CHINA SERIES B-CHEMISTRY
SICI code
1001-652X(199904)42:2<170:ANPETR>2.0.ZU;2-Q
Abstract
U. V. irradiation of N-alkylphenothiazines (1a-c) in carbon tetrachloride p
roduced 3-(phenothiazin-N'-yl-carbonyl)-N'-alkylphenothiazine (2a-b) and/or
3-( N'-alkylphenothiazin-3'-yl-carbonyl)-N-alkylphenothiazine (3b-c) toget
her with the radical cation carbon tetrachloride salt 1(+.)CCl(4)(-.)(4a-c)
, presumably via a photoinduced electron transfer mechanism.