P. Gurkan et N. Sari, Yttrium(III), cerium(III) and lanthanum(III) complexes of salicylideneamino acids, synthesis, characterization and potentiometric studies, SYN REAC IN, 29(5), 1999, pp. 753-765
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
New complexes of Y(III), Ce(III) and La(III) with Schiff bases derived from
the condensation reaction of salicylaldehyde with DL-glycine, DL-alanine a
nd DL-valine have been synthesized and characterized by elemental analyses,
molar conductivities, magnetic moments, infrared, H-1 NMR, electronic spec
tral data, and thermal analyses. The protonation constants of the Schiff ba
ses and stability constants of their ML-type complexes have been determined
potentiometrically at 25+/-0.1 degrees C and mu = 0.1 M KCl in aqueous sol
utions.