Yttrium(III), cerium(III) and lanthanum(III) complexes of salicylideneamino acids, synthesis, characterization and potentiometric studies

Authors
Citation
P. Gurkan et N. Sari, Yttrium(III), cerium(III) and lanthanum(III) complexes of salicylideneamino acids, synthesis, characterization and potentiometric studies, SYN REAC IN, 29(5), 1999, pp. 753-765
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
5
Year of publication
1999
Pages
753 - 765
Database
ISI
SICI code
0094-5714(1999)29:5<753:YCALCO>2.0.ZU;2-C
Abstract
New complexes of Y(III), Ce(III) and La(III) with Schiff bases derived from the condensation reaction of salicylaldehyde with DL-glycine, DL-alanine a nd DL-valine have been synthesized and characterized by elemental analyses, molar conductivities, magnetic moments, infrared, H-1 NMR, electronic spec tral data, and thermal analyses. The protonation constants of the Schiff ba ses and stability constants of their ML-type complexes have been determined potentiometrically at 25+/-0.1 degrees C and mu = 0.1 M KCl in aqueous sol utions.