PLE and HLE catalyzed reverse enantiomeric separation of (+/-)-methyl-2-methoxy-1-methyl-2,5-cyclohexadiene-1-carboxylate derivatives

Authors
Tanyeli, C Sezen, B Demir, AS Alves, RB Arseniyadis, S
Citation
C. Tanyeli et al., PLE and HLE catalyzed reverse enantiomeric separation of (+/-)-methyl-2-methoxy-1-methyl-2,5-cyclohexadiene-1-carboxylate derivatives, TETRAHEDR-A, 10(6), 1999, pp. 1129-1133
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
6
Year of publication
1999
Pages
1129 - 1133
Database
ISI
SICI code
0957-4166(19990326)10:6<1129:PAHCRE>2.0.ZU;2-J
Abstract
We describe the diversities of hydrolase-type enzymes PLE and HLE on the hy drolysis of (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-1-carboxyla te and (+/-)-methyl-2-methoxy-1 -methyl-2,5-cyclohexadiene-4-one-1-carboxyl ate to afford both enantiomers with 92-96% ee. (C) 1999 Elsevier Science Lt d. All rights reserved.