Carbenoid reactions of trifluoromethyl element compounds. 5. Difluoromethylation of amines with Zn(CF3)Br center dot 2 CH3CN, Cd(CF3)(2)center dot 2 CH3CN and the system Bi(CF3)(3)/AlCl3

Authors
Pasenok, SV Kirij, NV Yagupolskii, YL Naumann, D Tyrra, W Fitzner, A
Citation
Sv. Pasenok et al., Carbenoid reactions of trifluoromethyl element compounds. 5. Difluoromethylation of amines with Zn(CF3)Br center dot 2 CH3CN, Cd(CF3)(2)center dot 2 CH3CN and the system Bi(CF3)(3)/AlCl3, Z ANORG A C, 625(5), 1999, pp. 834-838
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
625
Issue
5
Year of publication
1999
Pages
834 - 838
Database
ISI
SICI code
0044-2313(199905)625:5<834:CROTEC>2.0.ZU;2-D
Abstract
The reactions of Zn(CF3)Br . 2 CH3CN, Cd(CF3)(2) . 2 CH3CN or Bi(CF3)3/AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts o f the general formula [R3NCF2H]X. The reaction of 4-N,N-dimethylaminopyridi ne with Zn(CF3)Br . 2 CH3CN yields (N-difluoromethyl)-4-N,N-dimethylaminopy ridinium bromide. Bi(CF3)(3)/AlCl3 reacts with 1,4-diazabicyclo[2.2.2]octan e to form a mixture of mono- and bis(difluoromethylammonium) salts.