Ions are ubiquitous in astrophysical environments. Knowledge of the cr
oss sections and rates for the atomic and molecular processes which cr
eate ions and which destroy them is an important part of any detailed
model of an astronomical object. Ions and ionic collisions in two very
different environments, the early Universe and planetary nebulae, are
explored in this paper. Electron-ion recombination leading to the eve
ntual formation of primordial molecules is described. Collisions of io
ns with electrons and atoms, central to the interpretation of emission
lines in astrophysical plasmas, are discussed. Recent work in predict
ing element abundances in planetary nebulae is highlighted.