The iron-mediated intramolecular addition of carboxylates to conjugated dienes

Authors
Yeh, MCP Chuang, LW Hsieh, YS Tsai, MS
Citation
Mcp. Yeh et al., The iron-mediated intramolecular addition of carboxylates to conjugated dienes, CHEM COMMUN, (9), 1999, pp. 805-806
Citations number
31
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
9
Year of publication
1999
Pages
805 - 806
Database
ISI
SICI code
1359-7345(19990507):9<805:TIIAOC>2.0.ZU;2-2
Abstract
Treatment of carboxylic acid functionalized (eta(4)-diene)-Fe(CO)(3) comple xes with 3.0 equiv, of NOBF4 in the presence of Et3N generates gamma- and d elta-lactones containing an alpha,beta-unsaturated aldehyde or oxime functi onality after NO+ insertion.